Anionic ring-opening polymerization of isobutylene oxide initiated with potassium salts activated by 18-crown-6: Determination of mechanism and characterization of polyether monols and diols

Various potassium salts, i.e., KOH, HOC3H6OC3H6OK, CH3OK, i-PrOK, t-BuOK, CbK, and (Me3Si)2NK activated by 18-crown-6 appeared to be active initiators of first anionic polymerization of isobutylene oxide. The processes were performed in mild conditions, i.e., tetrahydrofuran solution at room tempera...

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Bibliographic Details
Main Authors: Zbigniew Grobelny, Justyna Jurek-Suliga, Sylwia Golba
Format: Article
Language:English
Published: Budapest University of Technology 2022-05-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0011648&mi=cd