Diarylamine/diarylnitroxide cycle: quantum chemical and electrochemical estimation

Possibility for diarylamine/diarylnitroxide cycling via electrochemical N–O bond formation/bond breaking processes was considered using quantum-chemical and electrochemical methods. It was shown that electrochemically reduced diarylnitroxides undergo fast N–O bond cleavage in the presence of oxophil...

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Bibliographic Details
Main Authors: Oleg A. Levitskiy, Vyacheslav V. Sentyurin, Tatiana V. Magdesieva
Format: Article
Language:English
Published: Elsevier 2019-10-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844019363959