Why base-catalyzed isomerization of N-propargyl amides yields mostly allenamides rather than ynamides
The base-catalyzed isomerization of N-propargylamides or carbamates may furnish N-allenyl compounds (allenamides/allencarbamates) or further evolve to N-alkynyl compounds (ynamides or yncarbamates). The particular fate of this reaction varies from experiment to experiment and there is no clear rule...
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2015-08-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.11.156 |