Altered polar character of nanoconfined liquid water
Atomistic molecular dynamics simulation study of dipolar fluids confined to spherical nanocavities of radii ranging from R_{c}=1 to 4 nm reveals a surprisingly small Kirkwood correlation factor (g_{K}) in water, but not so in dipolar Stockmayer fluid. This results in an ultrafast relaxation of the t...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Physical Society
2019-12-01
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| Series: | Physical Review Research |
| Online Access: | http://doi.org/10.1103/PhysRevResearch.1.033145 |