Influence of Substituents in a Six-Membered Chelate Ring of HG-Type Complexes Containing an N→Ru Bond on Their Stability and Catalytic Activity

Influence of Substituents in a Six-Membered Chelate Ring of HG-Type Complexes Containing an N→Ru Bond on Their Stability and Catalytic Activity

An efficient approach to the synthesis of olefin metathesis HG-type catalysts containing an N→Ru bond in a six-membered chelate ring was proposed. For the most part, these ruthenium chelates can be prepared easily and in high yields based on the interaction between 2-vinylbenzylamines and <b>I...

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Bibliographic Details
Main Authors: Kirill A. Vasilyev, Alexandra S. Antonova, Nikita S. Volchkov, Nikita A. Logvinenko, Eugeniya V. Nikitina, Mikhail S. Grigoriev, Anton P. Novikov, Vladimir V. Kouznetsov, Kirill B. Polyanskii, Fedor I. Zubkov
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
ruthenium complexes
Hoveyda-Grubbs-type catalysts
ring-closing metathesis (RCM)
nitrogen-ruthenium coordinate bond
six-membered chelate cycle
[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene](dichloro)[benzylidene]ruthenium
Online Access:https://www.mdpi.com/1420-3049/28/3/1188

Internet

https://www.mdpi.com/1420-3049/28/3/1188

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