Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries

SiO<sub>x</sub> thin films were prepared using magnetron sputtering with different O<sub>2</sub> flow rates on a silicon substrate. The samples were characterized using Fourier transform infrared spectroscopy in transmission and reflection, covering a spectral range of 5 to 2...

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Main Authors: Natalia Herguedas, Enrique Carretero
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/20/2749
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author Natalia Herguedas
Enrique Carretero
author_facet Natalia Herguedas
Enrique Carretero
author_sort Natalia Herguedas
collection DOAJ
description SiO<sub>x</sub> thin films were prepared using magnetron sputtering with different O<sub>2</sub> flow rates on a silicon substrate. The samples were characterized using Fourier transform infrared spectroscopy in transmission and reflection, covering a spectral range of 5 to 25 μm. By employing a multilayer model, the values of the complex refractive index that best fit the experimental transmission and reflection results were optimized using the Brendel–Bormann oscillator model. The results demonstrate the significance of selecting an appropriate range of O<sub>2</sub> flow rates to modify the SiO<sub>x</sub> stoichiometry, as well as how the refractive index values can be altered between those of Si and SiO<sub>2</sub> in the mid-infrared range.
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spelling doaj.art-4b445a92cbde4f28a54351a8dd9e26082023-11-19T17:35:32ZengMDPI AGNanomaterials2079-49912023-10-011320274910.3390/nano13202749Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different StoichiometriesNatalia Herguedas0Enrique Carretero1Departamento de Física Aplicada, Universidad de Zaragoza, C/Pedro Cerbuna, 12, 50009 Zaragoza, SpainDepartamento de Física Aplicada, Universidad de Zaragoza, C/Pedro Cerbuna, 12, 50009 Zaragoza, SpainSiO<sub>x</sub> thin films were prepared using magnetron sputtering with different O<sub>2</sub> flow rates on a silicon substrate. The samples were characterized using Fourier transform infrared spectroscopy in transmission and reflection, covering a spectral range of 5 to 25 μm. By employing a multilayer model, the values of the complex refractive index that best fit the experimental transmission and reflection results were optimized using the Brendel–Bormann oscillator model. The results demonstrate the significance of selecting an appropriate range of O<sub>2</sub> flow rates to modify the SiO<sub>x</sub> stoichiometry, as well as how the refractive index values can be altered between those of Si and SiO<sub>2</sub> in the mid-infrared range.https://www.mdpi.com/2079-4991/13/20/2749thin filmoptical propertiesmid-infraredsilicon oxiderefractive index
spellingShingle Natalia Herguedas
Enrique Carretero
Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries
Nanomaterials
thin film
optical properties
mid-infrared
silicon oxide
refractive index
title Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries
title_full Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries
title_fullStr Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries
title_full_unstemmed Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries
title_short Optical Properties in Mid-Infrared Range of Silicon Oxide Thin Films with Different Stoichiometries
title_sort optical properties in mid infrared range of silicon oxide thin films with different stoichiometries
topic thin film
optical properties
mid-infrared
silicon oxide
refractive index
url https://www.mdpi.com/2079-4991/13/20/2749
work_keys_str_mv AT nataliaherguedas opticalpropertiesinmidinfraredrangeofsiliconoxidethinfilmswithdifferentstoichiometries
AT enriquecarretero opticalpropertiesinmidinfraredrangeofsiliconoxidethinfilmswithdifferentstoichiometries