Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels

The concept of this study is the replacement of previous fossil-based techniques for food packaging and food shelf-life extension, with novel more green processes and materials following the spirit of circular economy and the global trend for environmentally positive fingerprints. A novel adsorption...

Full description

Bibliographic Details
Main Authors: Constantinos E. Salmas, Aris E. Giannakas, Dimitrios Moschovas, Eleni Kollia, Stavros Georgopoulos, Christina Gioti, Areti Leontiou, Apostolos Avgeropoulos, Anna Kopsacheili, Learda Avdylaj, Charalampos Proestos
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/8/12/823
_version_ 1797457963186651136
author Constantinos E. Salmas
Aris E. Giannakas
Dimitrios Moschovas
Eleni Kollia
Stavros Georgopoulos
Christina Gioti
Areti Leontiou
Apostolos Avgeropoulos
Anna Kopsacheili
Learda Avdylaj
Charalampos Proestos
author_facet Constantinos E. Salmas
Aris E. Giannakas
Dimitrios Moschovas
Eleni Kollia
Stavros Georgopoulos
Christina Gioti
Areti Leontiou
Apostolos Avgeropoulos
Anna Kopsacheili
Learda Avdylaj
Charalampos Proestos
author_sort Constantinos E. Salmas
collection DOAJ
description The concept of this study is the replacement of previous fossil-based techniques for food packaging and food shelf-life extension, with novel more green processes and materials following the spirit of circular economy and the global trend for environmentally positive fingerprints. A novel adsorption process to produce thymol-halloysite nanohybrids is presented in this work. The high dispersion of this thymol-halloysite nanostructure in chitosan biopolymer is one of the goals of this study. The incorporation of this biodegradable matrix with poly-vinyl-alcohol produced a very promising food-packaging film. Mechanical, water-oxygen barrier, antimicrobial, and antioxidant properties were measured. Transparency levels were also tested using a UV-vis instrument. Moreover, the developed films were tested in-vivo for the preservation and the extension of the shelf-life of kiwi fruits. In all cases, results indicated that the increased fraction of thymol from thyme oil significantly enhances the antimicrobial and antioxidant activity of the prepared chitosan-poly-vinyl- alcohol gel. The use of the halloysite increases the mechanical and water-oxygen barrier properties and leads to a control release process of thymol which extends the preservation and the shelf-life of kiwi fruits. Finally, the results indicated that the halloysite improves the properties of the chitosan/poly-vinyl-alcohol films, and the thymol makes them further advantageous.
first_indexed 2024-03-09T16:31:19Z
format Article
id doaj.art-4b62a3392a724163a68bcd57cd11d76d
institution Directory Open Access Journal
issn 2310-2861
language English
last_indexed 2024-03-09T16:31:19Z
publishDate 2022-12-01
publisher MDPI AG
record_format Article
series Gels
spelling doaj.art-4b62a3392a724163a68bcd57cd11d76d2023-11-24T15:01:43ZengMDPI AGGels2310-28612022-12-0181282310.3390/gels8120823Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol GelsConstantinos E. Salmas0Aris E. Giannakas1Dimitrios Moschovas2Eleni Kollia3Stavros Georgopoulos4Christina Gioti5Areti Leontiou6Apostolos Avgeropoulos7Anna Kopsacheili8Learda Avdylaj9Charalampos Proestos10Department of Material Science and Engineering, University of Ioannina, 45110 Ioannina, GreeceDepartment of Food Science and Technology, University of Patras, 30100 Agrinio, GreeceDepartment of Material Science and Engineering, University of Ioannina, 45110 Ioannina, GreeceLaboratory of Food Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Zografou, 15771 Athens, GreeceDepartment of Food Science and Technology, University of Patras, 30100 Agrinio, GreeceDepartment of Material Science and Engineering, University of Ioannina, 45110 Ioannina, GreeceDepartment of Food Science and Technology, University of Patras, 30100 Agrinio, GreeceDepartment of Material Science and Engineering, University of Ioannina, 45110 Ioannina, GreeceLaboratory of Food Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Zografou, 15771 Athens, GreeceLaboratory of Food Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Zografou, 15771 Athens, GreeceLaboratory of Food Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Zografou, 15771 Athens, GreeceThe concept of this study is the replacement of previous fossil-based techniques for food packaging and food shelf-life extension, with novel more green processes and materials following the spirit of circular economy and the global trend for environmentally positive fingerprints. A novel adsorption process to produce thymol-halloysite nanohybrids is presented in this work. The high dispersion of this thymol-halloysite nanostructure in chitosan biopolymer is one of the goals of this study. The incorporation of this biodegradable matrix with poly-vinyl-alcohol produced a very promising food-packaging film. Mechanical, water-oxygen barrier, antimicrobial, and antioxidant properties were measured. Transparency levels were also tested using a UV-vis instrument. Moreover, the developed films were tested in-vivo for the preservation and the extension of the shelf-life of kiwi fruits. In all cases, results indicated that the increased fraction of thymol from thyme oil significantly enhances the antimicrobial and antioxidant activity of the prepared chitosan-poly-vinyl- alcohol gel. The use of the halloysite increases the mechanical and water-oxygen barrier properties and leads to a control release process of thymol which extends the preservation and the shelf-life of kiwi fruits. Finally, the results indicated that the halloysite improves the properties of the chitosan/poly-vinyl-alcohol films, and the thymol makes them further advantageous.https://www.mdpi.com/2310-2861/8/12/823thyme oilhalloysitechitosanpolyvinyl alcoholgelactive coatings
spellingShingle Constantinos E. Salmas
Aris E. Giannakas
Dimitrios Moschovas
Eleni Kollia
Stavros Georgopoulos
Christina Gioti
Areti Leontiou
Apostolos Avgeropoulos
Anna Kopsacheili
Learda Avdylaj
Charalampos Proestos
Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels
Gels
thyme oil
halloysite
chitosan
polyvinyl alcohol
gel
active coatings
title Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels
title_full Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels
title_fullStr Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels
title_full_unstemmed Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels
title_short Kiwi Fruits Preservation Using Novel Edible Active Coatings Based on Rich Thymol Halloysite Nanostructures and Chitosan/Polyvinyl Alcohol Gels
title_sort kiwi fruits preservation using novel edible active coatings based on rich thymol halloysite nanostructures and chitosan polyvinyl alcohol gels
topic thyme oil
halloysite
chitosan
polyvinyl alcohol
gel
active coatings
url https://www.mdpi.com/2310-2861/8/12/823
work_keys_str_mv AT constantinosesalmas kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT arisegiannakas kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT dimitriosmoschovas kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT elenikollia kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT stavrosgeorgopoulos kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT christinagioti kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT aretileontiou kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT apostolosavgeropoulos kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT annakopsacheili kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT leardaavdylaj kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels
AT charalamposproestos kiwifruitspreservationusingnoveledibleactivecoatingsbasedonrichthymolhalloysitenanostructuresandchitosanpolyvinylalcoholgels