Hydrogen Tunnelling as a Probe of the Involvement of Water Vibrational Dynamics in Aqueous Chemistry?

Hydrogen Tunnelling as a Probe of the Involvement of Water Vibrational Dynamics in Aqueous Chemistry?

Our study of tunnelling in proton-coupled electron transfer (PCET) oxidation of ascorbate with hexacyanoferrate(III) follows the insights obtained from ultrafast 2D IR spectroscopy and theoretical studies of the vibrational water dynamics that led to the proposal of the involvement of collective int...

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Bibliographic Details
Main Authors: Ana Karković Marković, Cvijeta Jakobušić Brala, Viktor Pilepić, Stanko Uršić
Format: Article
Language:English
Published: MDPI AG 2019-12-01
Series:Molecules
Subjects:
hydrogen tunnelling
kinetic isotope effects
water vibrational dynamics
aqueous reactivity
pcet reactions
ascorbate
Online Access:https://www.mdpi.com/1420-3049/25/1/172

Internet

https://www.mdpi.com/1420-3049/25/1/172

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