Syntheses, crystal structures and properties of tetrakis(3-methylpyridine-κN)bis(isothiocyanato-κN)manganese(II) and tetrakis(3-methylpyridine-κN)bis(isothiocyanato-κN)iron(II)

Syntheses, crystal structures and properties of tetrakis(3-methylpyridine-κN)bis(isothiocyanato-κN)manganese(II) and tetrakis(3-methylpyridine-κN)bis(isothiocyanato-κN)iron(II)

The reaction of Mn(NCS)2 or Fe(NCS)2 with 3-methylpyridine (C6H7N) leads to the formation of two isostructural compounds with compositions [Mn(NCS)2(C6H7N)4] (1) and [Fe(NCS)2(C6H7N)4] (2). IR spectroscopic investigations indicate that only terminally coordinated thiocyanate anions are present. This...

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Bibliographic Details
Main Authors: Magdalena Ceglarska, Christoph Krebs, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2022-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
manganese(ii)thiocyanate
3-methylpyridine
ir spectra
thermal properties
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022006491

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http://scripts.iucr.org/cgi-bin/paper?S2056989022006491

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