Syntheses, crystal structures and properties of tetrakis(3-methylpyridine-κN)bis(isothiocyanato-κN)manganese(II) and tetrakis(3-methylpyridine-κN)bis(isothiocyanato-κN)iron(II)
The reaction of Mn(NCS)2 or Fe(NCS)2 with 3-methylpyridine (C6H7N) leads to the formation of two isostructural compounds with compositions [Mn(NCS)2(C6H7N)4] (1) and [Fe(NCS)2(C6H7N)4] (2). IR spectroscopic investigations indicate that only terminally coordinated thiocyanate anions are present. This...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2022-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989022006491 |