Effects of Methyl Substitution and Leaving Group on E2/S<sub>N</sub>2 Competition for Reactions of F<sup>−</sup> with RY (R = CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub>, <sup>i</sup>C<sub>3</sub>H<sub>7</sub>, <sup>t</sup>C<sub>4</sub>H<sub>9</sub>; Y = Cl, I)

Effects of Methyl Substitution and Leaving Group on E2/S<sub>N</sub>2 Competition for Reactions of F<sup>−</sup> with RY (R = CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub>, <sup>i</sup>C<sub>3</sub>H<sub>7</sub>, <sup>t</sup>C<sub>4</sub>H<sub>9</sub>; Y = Cl, I)

The competition between base-induced elimination (E2) and bimolecular nucleophilic substitution (S<sub>N</sub>2) is of significant importance in organic chemistry and is influenced by many factors. The electronic structure calculations for the gas-phase reactions of F<sup>−</sup...

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Bibliographic Details
Main Authors: Wenqing Zhen, Siwei Zhao, Gang Fu, Hongyi Wang, Jianmin Sun, Li Yang, Jiaxu Zhang
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Molecules
Subjects:
base-induced elimination (E2)
nucleophilic substitution (S<sub>N</sub>2)
α-methyl substitution
electronic structure calculation
Online Access:https://www.mdpi.com/1420-3049/28/17/6269

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https://www.mdpi.com/1420-3049/28/17/6269

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