Electrochemical Studies of the Cycloaddition Activity of Bismuth(III) Acetylides Towards Organic Azides Under Copper(I)-Catalyzed Conditions

Electrochemical Studies of the Cycloaddition Activity of Bismuth(III) Acetylides Towards Organic Azides Under Copper(I)-Catalyzed Conditions

Time-dependent monitoring of the reactive intermediates provides valuable information about the mechanism of a synthetic transformation. However, the process frequently involves intermediates with short lifetimes that significantly challenge the accessibility of the desired kinetic data. We report i...

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Bibliographic Details
Main Authors: Antonina L. Nazarova, Billal Zayat, Valery V. Fokin, Sri R. Narayan
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-02-01
Series:Frontiers in Chemistry
Subjects:
cyclic voltammetry
mechanistic studies
bismuth(III) acetylides
reaction kinetic analysis
copper(I)catalysis
ordinary differential equations
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2022.830237/full

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https://www.frontiersin.org/articles/10.3389/fchem.2022.830237/full

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