Immobilization of Chiral Ferrocenyl Ligands on Silica Gel and their Testing in Pd-catalyzed Allylic Substitution and Rh-catalyzed Hydrogenation

Immobilization of Chiral Ferrocenyl Ligands on Silica Gel and their Testing in Pd-catalyzed Allylic Substitution and Rh-catalyzed Hydrogenation

Five different silica gels containing two chiral ferrocenyl ligands were prepared by various synthetic routes and tested in an enantioselective Pd(0)-catalyzed allylic substitution and Rh-catalyzed hydrogenation. All the prepared anchored ligands were characterized by porosimetry data, DRIFTS spectr...

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Bibliographic Details
Main Authors: Duncan J. Macquarrie, Mária Žembéryová, Štefan Toma, Ján Cvengroš
Format: Article
Language:English
Published: MDPI AG 2005-07-01
Series:Molecules
Subjects:
Heterogeneous catalysis
ferrocenylphosphane ligands
sol-gel-template method.
Online Access:http://www.mdpi.com/1420-3049/10/6/679/

Internet

http://www.mdpi.com/1420-3049/10/6/679/

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