Tuning the Catalytic Water Oxidation Activity through Structural Modifications of High-Nuclearity Mn-oxo Clusters [Mn<sub>18</sub>M] (M = Sr<sup>2+</sup>, Mn<sup>2+</sup>)

Tuning the Catalytic Water Oxidation Activity through Structural Modifications of High-Nuclearity Mn-oxo Clusters [Mn<sub>18</sub>M] (M = Sr<sup>2+</sup>, Mn<sup>2+</sup>)

The water oxidation half-reaction is considered the bottleneck in the development of technological advances to replace fossil fuels with sustainable and economically affordable energy sources. In natural photosynthesis, water oxidation occurs in the oxygen evolving complex (OEC), a manganese-oxo clu...

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Bibliographic Details
Main Authors: Joaquín Soriano-López, Rory Elliott, Amal C. Kathalikkattil, Ayuk M. Ako, Wolfgang Schmitt
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Water
Subjects:
water oxidation catalysis
oxygen evolution reaction
manganese
redox-active ligands
cubane-type structure
biomimetic catalyst
Online Access:https://www.mdpi.com/2073-4441/13/15/2042

Internet

https://www.mdpi.com/2073-4441/13/15/2042

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