Regiospecific α-methylene functionalisation of tertiary amines with alkynes via Au-catalysed concerted one-proton/two-electron transfer to O2
The selective α-methylene functionalization of tertiary amines is challenging. Here, the authors report the gold nanoparticles-catalyzed α-methylene alkynylation of tertiary amines via concerted one-proton/two-electron transfer to O2.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-34176-x |