Syntheses and structural characterization of heterometallic trinuclear {Cu(I), Ag(I)}-Ir(III) hydride complexes bridged by Ir metalloligands

Syntheses and structural characterization of heterometallic trinuclear {Cu(I), Ag(I)}-Ir(III) hydride complexes bridged by Ir metalloligands

The reactions of [Ir(H)2(PPh3)2(tptz)]PF6 (1) (tptz = 2,4,6-tris(2-pyridyl)-s-triazine) with {Cu(I), Ag(I)} salts under Ar afforded heterometallic trinuclear {Cu(I), Ag(I)}-Ir(III)-tptz hydride complexes [CuIr2(H)4(PPh3)4(tptz)2](PF6)3·2Me2CO (2), [AgIr2(H)4(PPh3)4(tptz)2](PF6)3·4Me2CO·H2O (3a) and...

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Bibliographic Details
Main Authors: Masahiko Maekawa, Shoki Oda, Kunihisa Sugimoto, Takashi Okubo, Takayoshi Kuroda-Sowa
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:Results in Chemistry
Subjects:
Heterometallic complexes
Copper complexes
Iridium complexes
Silver complexes
Hydride complexes
Metalloligands
Online Access:http://www.sciencedirect.com/science/article/pii/S2211715622002697

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http://www.sciencedirect.com/science/article/pii/S2211715622002697

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