Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido{2-[1-(dimethylamino)ethyl]benzylidene}ruthenium including an unknown solvate

Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido{2-[1-(dimethylamino)ethyl]benzylidene}ruthenium including an unknown solvate

The title compound, [RuCl2(C21H26N2)(C11H15N)], is an example of a new generation of N,N-dialkyl metallocomplex ruthenium catalysts with an N→Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison τ parameter of 0.234, which indicates a geometry intermediate between...

Full description

Bibliographic Details
Main Authors: Kirill B. Polyanskii, Kseniia A. Alekseeva, Pavel A. Kumandin, Zeliha Atioğlu, Mehmet Akkurt, Flavien A. A. Toze
Format: Article
Language:English
Published: International Union of Crystallography 2019-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
ruthenium catalyst
Hoveyda–Grubbs catalyst
N—Ru coordination bond
metathesis of olefins
SQUEEZE
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989019001725

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989019001725

Similar Items