Molecular <i>S</i> = 2 High-Spin, <i>S</i> = 0 Low-Spin and <i>S</i> = 0 ⇄ 2 Spin-Transition/-Crossover Nickel(II)-Bis(nitroxide) Coordination Compounds

Molecular <i>S</i> = 2 High-Spin, <i>S</i> = 0 Low-Spin and <i>S</i> = 0 ⇄ 2 Spin-Transition/-Crossover Nickel(II)-Bis(nitroxide) Coordination Compounds

Heterospin systems have a great advantage in frontier orbital engineering since they utilize a wide diversity of paramagnetic chromophores and almost infinite combinations and mutual geometries. Strong exchange couplings are expected in 3d–2p heterospin compounds, where the nitroxide (aminoxyl) oxyg...

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Bibliographic Details
Main Authors: Takayuki Ishida, Saki Ito, Yuta Homma, Yukiya Kyoden
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Inorganics
Subjects:
aminoxyl
exchange interaction
spin crossover
structural transition
switching behavior
magneto-structural relationship
Online Access:https://www.mdpi.com/2304-6740/9/2/10

Internet

https://www.mdpi.com/2304-6740/9/2/10

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