Hypervalent Nonbonded Interactions of a Divalent Sulfur Atom. Implications in Protein Architecture and the Functions

In organic molecules a divalent sulfur atom sometimes adopts weak coordination to a proximate heteroatom (X). Such hypervalent nonbonded S···X interactions can control the molecular structure and chemical reactivity of organic molecules, as well as their assembly and packing in the solid state. In t...

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Bibliographic Details
Main Authors: Noriyoshi Isozumi, Michio Iwaoka
Format: Article
Language:English
Published: MDPI AG 2012-06-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/17/6/7266