Synthesis and Characterization of a Novel Triangular Rh2Au Cluster Compound Inspired by the Isolobality Concept
Abstract The synthesis of [Rh2(η5‐Cp)2(μ‐H)(μ‐PPh2)2]BF4 (2) by protonation reaction of the metal basic complex [Rh2(η5‐Cp)2(μ‐PPh2)2] (1) with tetrafluoroboric acid in diethyl ether is described. Complex salt 2 was obtained in high yield and fully characterized by spectroscopic means and X‐ray crys...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2020-10-01
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| Series: | ChemistryOpen |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/open.202000217 |