Salen-like Chromium and Aluminum Complexes as Catalysts in the Copolymerization of Epoxides with Cyclic Anhydrides for the Synthesis of Polyesters

Salen-like Chromium and Aluminum Complexes as Catalysts in the Copolymerization of Epoxides with Cyclic Anhydrides for the Synthesis of Polyesters

Chromium and aluminum complexes bearing salalen ligands were explored as catalysts for the ring-opening copolymerization (ROCOP) of succinic (SA), maleic (MA), and phthalic (PA) anhydrides with several epoxides: cyclohexene oxide (CHO), propylene oxide (PO), and limonene oxide (LO). Their behavior w...

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Bibliographic Details
Main Authors: Federica Santulli, Ilaria Grimaldi, Daniela Pappalardo, Marina Lamberti, Mina Mazzeo
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:International Journal of Molecular Sciences
Subjects:
aluminum catalysts
block copolymers
chromium(III) catalysts
polyesters
ring opening copolymerization
switch catalysis
Online Access:https://www.mdpi.com/1422-0067/24/12/10052

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https://www.mdpi.com/1422-0067/24/12/10052

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