Unusual polarities of tetraalkylphosphonium and trialkylsulfonium ionic liquids, ylides, and carboxylated zwitterions

Aprotic heterocyclic anions (AHAs) can abstract hydrogen atoms from the methylene groups of the trialkylsulfonium and tetraalkylphosphonium cation. The resulting trialkylsulfonium and tetraalkylphosphonium ylides readily capture CO2 and produce unusual carboxylated zwitterions, in which the distance...

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Bibliographic Details
Main Authors: Vitaly V. Chaban, Nadezhda A. Andreeva
Format: Article
Language:English
Published: Elsevier 2023-12-01
Series:Journal of Ionic Liquids
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772422023000204