A Modular Approach to Atropisomeric Bisphosphines of Diversified Electronic Density on Phosphorus Atoms

A Modular Approach to Atropisomeric Bisphosphines of Diversified Electronic Density on Phosphorus Atoms

The series of <i>C<sub>2</sub></i>-symmetric biaryl core-based non-racemic bisphosphines possessing substituents of different electronic properties: both EDG and EWG were obtained in a short sequence of good yielding transformations, started from commercial 1,3-dimethyl-2-nit...

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Bibliographic Details
Main Authors: Oleg M. Demchuk, Aleksandra Martyna, Mateusz Kwaśnik, Katarzyna Szwaczko, Dorota Strzelecka, Barbara Mirosław, Kazimierz Michał Pietrusiewicz, Zofia Urbanczyk-Lipkowska
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Molecules
Subjects:
axially chiral biaryls
atropisomers
chiral bisphosphines
<i>C<sub>2</sub></i>-symmetry
CP-bond formation
enantiomer separation
Online Access:https://www.mdpi.com/1420-3049/27/17/5504

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https://www.mdpi.com/1420-3049/27/17/5504

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