Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases

Insights into Triazolylidene Ligands Behaviour at a Di-Iron Site Related to [FeFe]-Hydrogenases

The behaviour of triazolylidene ligands coordinated at a {Fe<sub>2</sub>(CO)<sub>5</sub>(µ-dithiolate)} core related to the active site of [FeFe]-hydrogenases have been considered to determine whether such carbenes may act as redox electron-reservoirs, with innocent or non-in...

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Bibliographic Details
Main Authors: Andrea Mele, Federica Arrigoni, Catherine Elleouet, François Y. Pétillon, Philippe Schollhammer, Giuseppe Zampella
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Molecules
Subjects:
non-innocent ligand
redox ligand
mesoionic carbene
triazolylidene
DFT calculations
di-iron complexes
Online Access:https://www.mdpi.com/1420-3049/27/15/4700

Internet

https://www.mdpi.com/1420-3049/27/15/4700

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