Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer

Anionic Polymerization of Para-Diethynylbenzene: Synthesis of a Strictly Linear Polymer

Anionic homo- and copolymerization of <i>p</i>-diethynylbenzene in the presence of n-BuLi in polar solvents was carried out. The use of hexamethylphosphortriamide (HMPA) makes it possible to synthesize a completely linear soluble polymer that does not have branching and phenylene fragmen...

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Bibliographic Details
Main Authors: Vyacheslav M. Misin, Irina E. Maltseva, Alexander A. Maltsev, Alexander V. Naumkin, Mark E. Kazakov
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Polymers
Subjects:
poly-<i>p</i>-diethynylbenzene
diphenyldiacetylene
anionic polymerization
n-butyllithium
heat resistance
thermal oxidation stability
Online Access:https://www.mdpi.com/2073-4360/14/5/900

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https://www.mdpi.com/2073-4360/14/5/900

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