Copolymerization of 1-hexene and 1-dodecene with 1,3-butadiene by a versatate/diisobutylaluminum hydride/t-butyl chloride catalyst system

The aim of this study was to incorporate an alpha-olefin (1-hexene or 1-dodecene) in a high cis polybutadiene chain, using a neodymium versatate/diisobutylaluminum hydride/t-butyl chloride catalyst system. The influence of alpha-olefin on polymerization reaction and polymer characteristics, using di...

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Bibliographic Details
Main Authors: Gustavo Monteiro da Silva, Ivana Lourenço de Mello Ferreira, Marcia Parente Melo da Costa, Neusa Maria Tocchetto Pires, Marcos Antonio da Silva Costa
Format: Article
Language:English
Published: Associação Brasileira de Polímeros 2014-01-01
Series:Polímeros
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282014000200004&lng=en&tlng=en