Tris(pentafluorophenyl)borane-catalyzed Hydride Transfer Reactions in Polysiloxane Chemistry—Piers–Rubinsztajn Reaction and Related Processes

Tris(pentafluorophenyl)borane-catalyzed Hydride Transfer Reactions in Polysiloxane Chemistry—Piers–Rubinsztajn Reaction and Related Processes

Tris(pentafluorophenyl)borane (TPFPB) is a unique Lewis acid that catalyzes the condensation between hydrosilanes (Si-H) and alkoxysilanes (Si-OR), leading to the formation of siloxane bonds (Si-OSi) with the release of hydrocarbon (R-H) as a byproduct—the so-called Piers–Rubinsztajn reaction. The a...

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Bibliographic Details
Main Authors: Slawomir Rubinsztajn, Julian Chojnowski, Urszula Mizerska
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Molecules
Subjects:
tris(pentafluorophenyl)borane
Piers–Rubinsztajn reaction
mechanism
dehydrocarbonative condensation
dehydrogenative condensation
hydride transfer polymerization
Online Access:https://www.mdpi.com/1420-3049/28/16/5941

Internet

https://www.mdpi.com/1420-3049/28/16/5941

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