Characterization of Diastereomeric Equilibria of Pseudotetrahedral Bis[(R or S)‐N‐1‐(Ar)Ethylsalicylaldiminato‐κ2N,O]zinc(II) with Λ/Δ‐Chirality‐At‐Metal Induction

Characterization of Diastereomeric Equilibria of Pseudotetrahedral Bis[(R or S)‐N‐1‐(Ar)Ethylsalicylaldiminato‐κ2N,O]zinc(II) with Λ/Δ‐Chirality‐At‐Metal Induction

Abstract A family of bis[(R or S)‐N‐1‐(Ar)ethylsalicylaldiminato‐κ2N,O]‐Δ/Λ‐zinc(II) {Ar=C6H5 (ZnRL1 or ZnSL1), p‐CH3OC6H4 (ZnRL2 or ZnSL2) and p‐ClC6H4 (ZnRL3 or ZnSL3)} compounds was synthesized and investigated by multiple methods. They feature Λ/Δ‐chirality‐at‐metal induction along the pseudo‐C2...

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Bibliographic Details
Main Authors: Prof. Dr. Mohammed Enamullah, Mohammad Mostafizur Rahman, Mohammad Khairul Islam, Dr. Dennis Woschko, Prof. Dr. Christoph Janiak, Prof. Dr. Gennaro Pescitelli
Format: Article
Language:English
Published: Wiley-VCH 2022-07-01
Series:ChemistryOpen
Subjects:
chirality
diastereomeric equilibrium
metal complexes
Schiff base ligand
spectroscopic investigation
Online Access:https://doi.org/10.1002/open.202200116

Internet

https://doi.org/10.1002/open.202200116

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