Opposite Effects of the Rotational and Translational Energy on the Rates of Ion-Molecule Reactions near 0 K: The D_{2}^{+}+NH_{3} and D_{2}^{+}+ND_{3} Reactions
The ion-molecule reactions D_{2}^{+}+NH_{3} and D_{2}^{+}+ND_{3} are studied at low collision energies (E_{coll} from zero to approximately k_{B}×50 K), with the D_{2}^{+} ions in the ground rovibrational state and for different rotational temperatures of the ammonia molecules, using the Rydberg-St...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Physical Society
2024-03-01
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| Series: | Physical Review X |
| Online Access: | http://doi.org/10.1103/PhysRevX.14.011034 |