Cryostructuring of Polymeric Systems. 49. Unexpected “Kosmotropic-Like” Impact of Organic Chaotropes on Freeze–Thaw-Induced Gelation of PVA in DMSO

Urea (URE) and guanidine hydrochloride (GHC) possessing strong chaotropic properties in aqueous media were added to DMSO solutions of poly(vinyl alcohol) (PVA) to be gelled via freeze–thaw processing. Unexpectedly, it turned out that in the case of the PVA cryotropic gel formation in DMSO...

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Bibliographic Details
Main Authors: Vladimir I. Lozinsky, Olga Yu. Kolosova, Dmitrii A. Michurov, Alexander S. Dubovik, Viktor G. Vasil’ev, Valerij Ya. Grinberg
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Gels
Subjects:
Online Access:http://www.mdpi.com/2310-2861/4/4/81