A Series of Cube-Shaped Polyoxoniobates Encapsulating Octahedral Cu12XmOn Clusters With Hydrolytic Decomposition for Chemical Warfare Agents

This study reported a series of cube-shaped polyoxoniobates, {MCu12O8)(Cu12XmOn)(Nb7(OH)O21)8} [M = Nb(1, 2), Ln3+(3), X = I(1, m = 3, n = 3; 2, m = 5, n = 1), Br(3, m = 5, n = 1)]. As the first octahedral Cu12XmOn cluster incorporated polyoxoniobate, the cube-shaped three-shell structure of {MCu12O...

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Bibliographic Details
Main Authors: Yan-Lan Wu, Rong-Tao Zhang, Yan-Qiong Sun, Xin-Xiong Li, Shou-Tian Zheng
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-12-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2020.586009/full