[(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study

[(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study

The title phosphanegold(I) thiolate, C26H22AuFNOPS or [Au(C8H7FNOS)(C18H15P)], has the AuI centre coordinated by phosphane-P [2.2494 (8) Å] and thiolate-S [2.3007 (8) Å] atoms to define a close to linear geometry [P—Au—S = 176.10 (3)°]. The thiolate ligand is orientated so that the methoxy-O atom is...

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Bibliographic Details
Main Authors: Chien Ing Yeo, Sang Loon Tan, Huey Chong Kwong, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2020-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
gold
thiocarbamate
hirshfeld surface analysis
computational chemistry
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020009469

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http://scripts.iucr.org/cgi-bin/paper?S2056989020009469

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