Comparison of the crystal structures of the low- and high-temperature forms of bis[4-(dimethylamino)pyridine]dithiocyanatocobalt(II)

Comparison of the crystal structures of the low- and high-temperature forms of bis[4-(dimethylamino)pyridine]dithiocyanatocobalt(II)

Single crystals of the high-temperature form I of [Co(NCS)2(DMAP)2] (DMAP = 4-dimethylaminopyridine, C7H10N2) were obtained accidentally by the reaction of Co(NCS)2 with DMAP at slightly elevated temperatures under kinetic control. This modification crystallizes in the monoclinic space group P21/m a...

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Bibliographic Details
Main Authors: Christoph Krebs, Inke Jess, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2021-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
polymorphism
cobalt(ii)thiocyanate
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021010422

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http://scripts.iucr.org/cgi-bin/paper?S2056989021010422

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