(3+2)-Cycloadditions of Levoglucosenone (LGO) with Fluorinated Nitrile Imines Derived from Trifluoroacetonitrile: An Experimental and Computational Study

(3+2)-Cycloadditions of Levoglucosenone (LGO) with Fluorinated Nitrile Imines Derived from Trifluoroacetonitrile: An Experimental and Computational Study

The in situ-generated <i>N</i>-aryl nitrile imines derived from trifluoroacetonitrile smoothly undergo (3+2)-cycloadditions onto the enone fragment of the levoglucosenone molecule, yielding the corresponding, five-membered cycloadducts. In contrast to the ‘classic’ <i>C</i>(P...

Full description

Bibliographic Details
Main Authors: Grzegorz Mlostoń, Katarzyna Urbaniak, Marcin Palusiak, Zbigniew J. Witczak, Ernst-Ulrich Würthwein
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Molecules
Subjects:
levoglucosenone
nitrile imines
(3+2)-cycloadditions
fluoroalkylated pyrazoles
DFT calculations
Online Access:https://www.mdpi.com/1420-3049/28/21/7348

Internet

https://www.mdpi.com/1420-3049/28/21/7348

Similar Items