Development of an additive-controlled, SmI2-mediated stereoselective sequence: Telescoped spirocyclisation, lactone reduction and Peterson elimination
Studies on SmI2-mediated spirocyclisation and lactone reduction culminate in a telescoped sequence in which additives are used to “switch on” individual steps mediated by the electron transfer reagent. The sequence involves the use of two activated SmI2 reagent systems and a silicon stereocontrol el...
| Auteurs principaux: | , , |
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| Format: | Article |
| Langue: | English |
| Publié: |
Beilstein-Institut
2013-07-01
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| Collection: | Beilstein Journal of Organic Chemistry |
| Sujets: | |
| Accès en ligne: | https://doi.org/10.3762/bjoc.9.163 |