Origin of the Ligand Ring‐Size Effect on the Catalytic Activity of Cationic Calcium Hydride Dimers in the Hydrogenation of Unactivated 1‐Alkenes
Abstract Recently, it was shown that the double Ca−H−Ca‐bridged calcium hydride cation dimer [LCaH2CaL]2+ when stabilized by a larger macrocyclic N,N’,N’’,N’’’,N’’’’‐pentadentate ligand showed evidently higher activity than when stabilized by a smaller N,N’,N’’,N’’’‐tetradentate ligand in the cataly...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2022-12-01
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| Series: | ChemistryOpen |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/open.202200240 |