The Cathodic Cleavage of the Nitrobenzoyl Group from Protected Aliphatic Amines in N,N-Dimethylformamide

The electrochemical reduction of aliphatic amines protected by the 4- and 3- nitrobenzoyl group in N,N-dimethylformamide was reported. The compounds are reduced in two cathodic steps. The first one at about -1 V vs. SCE occurs with the formation of the rather stable anion radicals, involving one ele...

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Bibliographic Details
Main Authors: Jorge Sônia Maria Alves, Campos Pedro Maia de, Stradiotto Nelson Ramos
Format: Article
Language:English
Published: Sociedade Brasileira de Química 1999-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531999000300003