σ-Aromatic MAl<sub>6</sub>S<sub>6</sub> (M = Ni, Pd, Pt) Stars Containing Planar Hexacoordinate Transition Metals

σ-Aromatic MAl<sub>6</sub>S<sub>6</sub> (M = Ni, Pd, Pt) Stars Containing Planar Hexacoordinate Transition Metals

Hypercoordinate transition-metal species are mainly dominated by the 18-valence-electron (18ve) counting. Herein, we report ternary MAl<sub>6</sub>S<sub>6</sub> (M = Ni, Pd, Pt) clusters with the planar hexacoordinate metal (phM) centers, which feature 16ve counting instead o...

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Bibliographic Details
Main Authors: Li-Xia Bai, Jin-Chang Guo
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
planar hexacoordinate metal (phM) clusters
global minimum
chemical bonding
16-valence-electron counting
σ aromaticity
Online Access:https://www.mdpi.com/1420-3049/28/3/942

Internet

https://www.mdpi.com/1420-3049/28/3/942

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