Mechanistics of pH-Dependent Sulfmyoglobin Formation: Spin Control and His64 Proton Relay

The chemistry of hydrogen sulfide (H2S) has been directed towards physiologically relevant hemeproteins, including myoglobin, hemoglobin, and other similar proteins. Despite substantial efforts, there remains a need to elucidate the mechanism and identify the species involved in the reaction between...

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Bibliographic Details
Main Authors: Angel D. Rodriguez-Mackenzie, Lysmarie Santos-Velazquez, Héctor D. Arbelo-Lopez, Troy Wymore, Juan Lopez-Garriga
Format: Article
Language:English
Published: Hindawi Limited 2024-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2024/4244579