Iminoiodane- and Brønsted Base-Mediated Cross Dehydrogenative Coupling of Cyclic Ethers with 1,3-Dicarbonyl Compounds

Iminoiodane- and Brønsted Base-Mediated Cross Dehydrogenative Coupling of Cyclic Ethers with 1,3-Dicarbonyl Compounds

A one-pot, two-step approach to prepare 2-tetrahydrofuran and -pyran substituted 1,3-dicarbonyl compounds by PhI=NTs-mediated amination/Brønsted base-catalyzed cross dehydrogenative coupling (CDC) reaction of the cyclic ether and 1,3-dicarbonyl derivative under mild conditions is reported. The react...

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Bibliographic Details
Main Authors: Ciputra Tejo, Xiao Rong Sim, Bo Ra Lee, Benjamin James Ayers, Chung-Hang Leung, Dik-Lung Ma, Philip Wai Hong Chan
Format: Article
Language:English
Published: MDPI AG 2015-07-01
Series:Molecules
Subjects:
C–C bond formation
cross dehydrogenation coupling
1,3-dicarbonyl compounds
iminoiodanes
metal-free catalysis
Online Access:http://www.mdpi.com/1420-3049/20/7/13336

Internet

http://www.mdpi.com/1420-3049/20/7/13336

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