Effect of Alkylation on the Kinetic Stability of Arsenodiester and Organoarsenicals against Hydrolysis: A Theoretical Study

Arsenic diesters have same structural and chemical properties as Pi (phosphate) diester. Beside this structural similarity, arsenate is not considered by cellular processes to replace phosphate. Quantum calculation reveals that this happens due to very high hydrolysis rate of Asi diester (As–O-bond-...

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Príomhchruthaitheoirí: Boota Singh, Rohan Ranjan Waliya, Sougata Santra, Kousik Giri, Grigory V. Zyryanov
Formáid: Alt
Teanga:English
Foilsithe / Cruthaithe: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2018-07-01
Sraith:Chimica Techno Acta
Ábhair:
Rochtain ar líne:https://chimicatechnoacta.ru/article/view/3170