Halogen-bonded network of trinuclear copper(II) 4-iodopyrazolate complexes formed by mutual breakdown of chloroform and nanojars

Halogen-bonded network of trinuclear copper(II) 4-iodopyrazolate complexes formed by mutual breakdown of chloroform and nanojars

Crystals of bis(tetrabutylammonium) di-μ3-chlorido-tris(μ2-4-iodopyrazolato-κ2N:N′)tris[chloridocuprate(II)] 1,4-dioxane hemisolvate, (C16H36N)2[Cu3(C3H2IN2)3Cl5]·0.5C4H8O or (Bu4N)2[CuII3(μ3-Cl)2(μ-4-I-pz)3Cl3]·0.5C4H8O, were obtained by evaporating a solution of (Bu4N)2[{CuII(μ-OH)(μ-4-I-pz)}nCO3]...

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Bibliographic Details
Main Authors: Stuart A. Surmann, Gellert Mezei
Format: Article
Language:English
Published: International Union of Crystallography 2016-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper pyrazolate
trinuclear complex
nanojar
halogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901601536X

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http://scripts.iucr.org/cgi-bin/paper?S205698901601536X

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