Effect of substrate and catalyst chirality on the diastereoselective epoxidation of R-(+)-limonene with manganese(III) salen complexes

Effect of substrate and catalyst chirality on the diastereoselective epoxidation of R-(+)-limonene with manganese(III) salen complexes

The asymmetric epoxidation of R-(+)-limonene in the presence of the Jacobsen´s catalyst in its chiral and achiral either homogeneous or heterogeneous (immobilized on Al-MCM-41) forms was studied using in situ generated dimethyldioxirane as oxidizing agent. It was found that the catalytic activity o...

Full description

Bibliographic Details
Main Authors: Juliana Reyes, Jairo Antonio Cubillos, Aída Luz Villa, Consuelo Montes de Correa
Format: Article
Language:English
Published: Universidad de Antioquia 2013-07-01
Series:Revista Facultad de Ingeniería Universidad de Antioquia
Subjects:
R-( )-limonene
enantiomerically pure epoxides
asymmetric synthesis
manganese (III) salen complexes
optically active catalysts
achiral catalyst
Online Access:https://revistas.udea.edu.co/index.php/ingenieria/article/view/16005

Internet

https://revistas.udea.edu.co/index.php/ingenieria/article/view/16005

Similar Items