Design and synthesis of novel bis-annulated caged polycycles via ring-closing metathesis: pushpakenediol
Intricate caged molecular frameworks are assembled by an atom economical process via a Diels–Alder (DA) reaction, a Claisen rearrangement, a ring-closing metathesis (RCM) and an alkenyl Grignard addition. The introduction of olefinic moieties in the pentacycloundecane (PCUD) framework at appropriate...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2014-11-01
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Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.10.280 |