Tributyl(1-((dimethylamino)(dimethyliminio)methyl)-1,4-dihydropyridin-4-yl)phosphonium Ditrifluoromethanesulfonate

Tributyl(1-((dimethylamino)(dimethyliminio)methyl)-1,4-dihydropyridin-4-yl)phosphonium Ditrifluoromethanesulfonate

Site-selective functionalization of pyridines is a crucial tool for the synthesis of diverse pharmaceuticals and materials. We introduced diiminium pyridine adducts as highly convenient and potent Lewis acids. We report that tributylphosphine selectively adds to the 4-position of pyridine in tetrame...

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Bibliographic Details
Main Authors: Yiwei Gong, Jas S. Ward, Kari Rissanen, Florian F. Mulks
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Molbank
Subjects:
pyridine functionalization
dihydropyridine
Lewis acids
organic Lewis acids
dications
diiminium
Online Access:https://www.mdpi.com/1422-8599/2023/3/M1710

Internet

https://www.mdpi.com/1422-8599/2023/3/M1710

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