Crystal structure of bis{μ2-[(2-iminocyclopentylidene)methylidene]azanido-κ2N:N′}bis[(η5-pentamethylcyclopentadienyl)zirconium(IV)] hexane monosolvate

Crystal structure of bis{μ2-[(2-iminocyclopentylidene)methylidene]azanido-κ2N:N′}bis[(η5-pentamethylcyclopentadienyl)zirconium(IV)] hexane monosolvate

The title compound, [Zr2(C10H15)4(C6H6N2)2]·C6H14, was obtained by the stoichiometric reaction of adiponitrile with [Zr(C10H15)2(η2-Me3SiC2SiMe3)]. Intramolecular nitrile–nitrile couplings and deprotonation of the substrate produced the (1-imino-2-enimino)cyclopentane ligand, which functions as a fi...

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Bibliographic Details
Main Authors: Lisanne Becker, Anke Spannenberg, Perdita Arndt, Uwe Rosenthal
Format: Article
Language:English
Published: International Union of Crystallography 2015-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
dinuclear structure
zirconocene
1-imino-2-enimino-cyclopentane ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015021234

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http://scripts.iucr.org/cgi-bin/paper?S2056989015021234

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