Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid

Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid

Designing catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon diox...

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Bibliographic Details
Main Authors: Athanasios Zavras, George N. Khairallah, Marjan Krstić, Marion Girod, Steven Daly, Rodolphe Antoine, Philippe Maitre, Roger J. Mulder, Stefanie-Ann Alexander, Vlasta Bonačić-Koutecký, Philippe Dugourd, Richard A. J. O’Hair
Format: Article
Language:English
Published: Nature Portfolio 2016-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/ncomms11746

Internet

https://doi.org/10.1038/ncomms11746

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