Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
Designing catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon diox...
| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2016-06-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms11746 |
| _version_ | 1818342757995905024 |
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| author | Athanasios Zavras George N. Khairallah Marjan Krstić Marion Girod Steven Daly Rodolphe Antoine Philippe Maitre Roger J. Mulder Stefanie-Ann Alexander Vlasta Bonačić-Koutecký Philippe Dugourd Richard A. J. O’Hair |
| author_facet | Athanasios Zavras George N. Khairallah Marjan Krstić Marion Girod Steven Daly Rodolphe Antoine Philippe Maitre Roger J. Mulder Stefanie-Ann Alexander Vlasta Bonačić-Koutecký Philippe Dugourd Richard A. J. O’Hair |
| author_sort | Athanasios Zavras |
| collection | DOAJ |
| description | Designing catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon dioxide from formic acid. |
| first_indexed | 2024-12-13T16:19:46Z |
| format | Article |
| id | doaj.art-5c9942ddd8b84c90bbfe868edef555cf |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-13T16:19:46Z |
| publishDate | 2016-06-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-5c9942ddd8b84c90bbfe868edef555cf2022-12-21T23:38:45ZengNature PortfolioNature Communications2041-17232016-06-01711810.1038/ncomms11746Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acidAthanasios Zavras0George N. Khairallah1Marjan Krstić2Marion Girod3Steven Daly4Rodolphe Antoine5Philippe Maitre6Roger J. Mulder7Stefanie-Ann Alexander8Vlasta Bonačić-Koutecký9Philippe Dugourd10Richard A. J. O’Hair11School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, The University of MelbourneSchool of Chemistry and Bio21 Molecular Science and Biotechnology Institute, The University of MelbourneCenter of Excellence for Science and Technology – Integration of Mediterranean region (STIM) at Interdisciplinary Center for Advanced Science and Technology (ICAST), University of SplitInstitut des Sciences Analytiques, Université de Lyon, Université Lyon 1-CNRS-ENS LyonInstitut Lumière Matière, Université Lyon 1-CNRS, Université de LyonInstitut Lumière Matière, Université Lyon 1-CNRS, Université de LyonLaboratoire de Chimie Physique, Bâtiment 349, Université Paris-Sud, CNRS, Université Paris-SaclayCSIRO ManufacturingSchool of Chemistry and Bio21 Molecular Science and Biotechnology Institute, The University of MelbourneCenter of Excellence for Science and Technology – Integration of Mediterranean region (STIM) at Interdisciplinary Center for Advanced Science and Technology (ICAST), University of SplitInstitut Lumière Matière, Université Lyon 1-CNRS, Université de LyonSchool of Chemistry and Bio21 Molecular Science and Biotechnology Institute, The University of MelbourneDesigning catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon dioxide from formic acid.https://doi.org/10.1038/ncomms11746 |
| spellingShingle | Athanasios Zavras George N. Khairallah Marjan Krstić Marion Girod Steven Daly Rodolphe Antoine Philippe Maitre Roger J. Mulder Stefanie-Ann Alexander Vlasta Bonačić-Koutecký Philippe Dugourd Richard A. J. O’Hair Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid Nature Communications |
| title | Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid |
| title_full | Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid |
| title_fullStr | Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid |
| title_full_unstemmed | Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid |
| title_short | Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid |
| title_sort | ligand induced substrate steering and reshaping of ag2 h scaffold for selective co2 extrusion from formic acid |
| url | https://doi.org/10.1038/ncomms11746 |
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