Ag<sub>2</sub>O versus Cu<sub>2</sub>O in the Catalytic Isomerization of Coordinated Diaminocarbenes to Formamidines: A Theoretical Study
DFT theoretical calculations for the Ag<sub>2</sub>O-induced isomerization process of diaminocarbenes to formamidines, coordinated to Mn(I), have been carried out. The reaction mechanism found involves metalation of an N-H residue of the carbene ligand by the catalyst Ag<sub>2</...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-01-01
|
| Series: | Materials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1996-1944/15/2/491 |