Animal Slurry Sanitization through pH Adjustment: Process Optimization and Impact on Slurry Characteristics

Sanitization by pH adjustment of dairy and pig slurries was evaluated for potential use as organic fertilizer in horticulture. This requires absence of <i>Salmonella</i> in 25 g of slurry and less than 1000 <i>Escherichi coli</i> colony-forming unit per gram of fresh slurry (...

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Bibliographic Details
Main Authors: Joana Rodrigues, Paula Alvarenga, Ana Carla Silva, Luísa Brito, Jorge Tavares, David Fangueiro
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Agronomy
Subjects:
Online Access:https://www.mdpi.com/2073-4395/11/3/517
Description
Summary:Sanitization by pH adjustment of dairy and pig slurries was evaluated for potential use as organic fertilizer in horticulture. This requires absence of <i>Salmonella</i> in 25 g of slurry and less than 1000 <i>Escherichi coli</i> colony-forming unit per gram of fresh slurry (Regulation (EU) 2019/1009). Additives used in the alkalinization and acidification treatments, included hydroxide-salts and nitrogen-based reactants to increase slurry pH to a basic range (9.0–11.0) and concentrated H<sub>2</sub>SO<sub>4</sub> to decrease slurry pH to an acidic range (5.5–3.5). While low-cost urea was unable to increase the slurry pH above 9.5, ammonia efficiently increased slurry pH to the targeted values (but enhanced the emissions risk), whereas the effect of Ca(OH)<sub>2</sub> was hindered by its low solubility. Slurry sanitization by alkalinization was achieved at a pH of 9.5 for both slurries, using similar quantities of KOH or NaOH. KOH was selected for further tests since it provides a plant macronutrient. Acidification with concentrated H<sub>2</sub>SO<sub>4</sub> was able to achieve sanitization by lowering the pH to 5.0. After a 60-d storage experiment with raw and treated slurries, the level of <i>E. coli</i> was below the sanitization limit for all samples. Storage had no significant impact on slurry characteristics, except for ammonium-nitrogen content. Acidification treatment minimized ammonia losses.
ISSN:2073-4395